By D. Michael P. Mingos
Chemical constitution and bonding. The scope of the sequence spans the whole Periodic desk and addresses constitution and bonding matters linked to the entire components. It additionally focuses recognition on new and constructing parts of contemporary structural and theoretical chemistry resembling nanostructures, molecular electronics, designed molecular solids, surfaces, steel clusters and supramolecular buildings. actual and spectroscopic recommendations used to figure out, learn and version constructions fall in the purview of constitution and Bonding to the level that the focal point is at the clinical effects bought and never on expert info about the recommendations themselves. concerns linked to the advance of bonding types and generalizations that remove darkness from the reactivity pathways and charges of chemical approaches also are appropriate. the person volumes within the sequence are thematic. The target of every quantity is to offer the reader, no matter if at a school or in undefined, a complete review of a space the place new insights are rising which are of curiosity to a bigger medical viewers. hence every one assessment in the quantity seriously surveys one point of that subject and areas it in the context of the amount as a complete. the main major advancements of the final five to ten years can be offered utilizing chosen examples to demonstrate the rules mentioned. an outline of the actual foundation of the experimental thoughts which have been used to supply the first facts can also be applicable, if it has now not been coated intimately in other places. The assurance don't need to be exhaustive in facts, yet should still otherwise be conceptual, focusing on the recent rules being built that might enable the reader, who's now not a expert within the sector coated, to appreciate the knowledge awarded. dialogue of attainable destiny study instructions within the quarter is welcomed. assessment articles for the person volumes are invited by means of the quantity editors.
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Additional resources for 50 Years of Structure and Bonding – The Anniversary Volume
2PF6À. 2PF6À (Table 2). An X-ray crystal structure of the bromide complex of 12+ is shown in Fig. 217(1) Å. A. 2PF6À. 2PF6À Anionb FÀ ClÀ BrÀ IÀ FÀ ClÀ BrÀ IÀ Ka (MÀ1)c –d <10 889 (37) 184 (15) –d 133 (12) 130 (10) 102 (7) a In 9:1 CD3OD/D2O at 295 K Anions have been used as a tetrabutylammonium salt c Obtained from monitoring the internal phenyl proton d No detectable evidence of binding observed; error in parentheses b Taylor and co-workers have combined hydrogen and halogen-bonding groups in a series of receptors including compound 14a .
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CrystEngComm 13:3293–3300 13. Schwans JP, Sunden F, Lassila JK, Gonzalez A, Tsai Y, Herschlag D (2013) Use of anionaromatic interactions to position the general base in the ketosteroid isomerase active site. Proc Natl Acad Sci U S A 110:11308–11313 14. Davis JT, Gale PA, Okunola OA, Prados P, Iglesias-Sa´nchez JC, Torroba T, Quesada R (2009) Using small molecules to facilitate exchange of bicarbonate and chloride anions across liposomal membranes. Nat Chem 1:138–144 15. Casey JR (2006) Why bicarbonate?
50 Years of Structure and Bonding – The Anniversary Volume by D. Michael P. Mingos