By István T. Horváth, Ferenc Joó
Within the final 15 years aqueous organometallic chemistry and catalysis has emerged from being a laboratory interest to develop into a longtime box of study. themes reviewed the following contain mechanistic reports at the impression of water on catalyzed reactions, the instruction of water soluble phosphines as ligands for catalysis, steel catalyzed natural reactions in water (hydrogenation, hydroformylation, carbonylation, olefin metathesis, hydrophosphination, etc.), chiral ligands and enantioselective catalysis, organometallic radical photochemistry in aqueous suggestions, bioorganometallic chemistry, organometallic reactions of biopolymers, and catalytic amendment of biomembranes. The precis of modern effects is supplemented by way of an review of possible destiny examine tendencies.
Audience: Researchers in either academia and undefined, in addition to graduate scholars of homogeneous catalysis.
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Additional info for Aqueous Organometallic Chemistry and Catalysis
And Ziller, J. W. (1992) Ring-Opening Metathesis Polymerization (ROMP) of Norbornene by a Group VIII Carbene Complex in Protic Media, J. Am. Chern. Soc. 114,3974-3975. 7. , Benedicto, A. , and Grubbs, R. H. 0]-heptene Catalyzed by a Ruthenium Alkylidene Complex, Macromolecules 26,4975-4977. 8. Nguyen, S. , Grubbs, R. H. and Ziller, J. W. (1993) Syntheses and Activities of New Single-Component, Ruthenium-based Olefin Metathesis Catalysts, 1. Am. Chern. Soc. 115, 9858-9859. 9. Nguyen, S. T. and Grubbs, R.
On standing at room temperature, aqueous solutions of 2 will deposit clear colorless crystals of facIrCI3(PMe3) (equation 4). The fate of the COD ligand in this transformation is g' . , +2 V/PMe3 _H20 ", Ir", PM 2 CI • 2HCI ~ 1 e3 PMe3 I Cl, CI I "", PMe3 CI"Y-PMe3 + ? (4) PMe3 unknown. Apparently, the extra equivalents of HCI are responsible for this reaction. PrQtonation of 1 produces a protonated complex, 3, which contains one chloride ion, one BF4 ion and one equivalent of HBF4 (equation 5).
1989) Chiral sulphonated phosphines ll. Influence of water on the enantioselectivity in the reduction of dehydroaminoacids, l. Organometal. Chern. 370,277-284 7. , Selke, R. (1992) Increase in activity and enantioselectivity in asymmetric hydrogenation reactions catalysed by chiral rhodium(I) complexes as a consequence of the action of amphiphiles, l. Mol. Catal. 71, LI-L5 8. Larpent, C. and Patin, H. (1988) Organic chemistry in water (part ll). Nucleophilic addition of water-soluble phosphines on activated olefins, Tetrahedron 44, 6107-6118 9.
Aqueous Organometallic Chemistry and Catalysis by István T. Horváth, Ferenc Joó